best quality 108-91-8 price Cyclohexylamine 108-91-8
Properties, application and production process of cyclohexylamine
The physical and chemical properties
Cyclohexylamine also known as amino cyclohexane, hexahydroaniline. Colorless transparent liquid. Intense smell of fish and ammonia. Flammable.
The molecular weight is 99.18.
The relative density was 0.8191.
Melting point - 17.7 ℃.
Boiling point 134.5 ℃, 118.9 ℃ (6.67 x 104 pa), 102.5 ℃ (4.00 x 104 pa), 72.0 ℃ (1.33 x 104 pa), 56.0 ℃ (6.67 x 103 pa), 45.1 ℃ (4.00 x 103 pa), 41.3 ℃ (3.33 x 103 pa), 36.4 ℃ (2.67 x 103 pa), 30.5 ℃ (1.99 x 103 pa), 25.0 ℃ (1.17 x 103 pa).
The refractive index is 1.4372.
Flash point 32 ℃.
Ignition point 265 ℃.
Soluble in water, can be miscible with ethanol, ether, acetone, ethyl acetate, chloroform, heptane, benzene and other general organic solvents. Cyclohexylamine can evaporate with water vapor. Carbonates that absorb carbon dioxide from the air and form white crystals. It forms an azeotropic substance with water at an azeotropic point of 96.4℃ and contains 55.8% water. The aqueous solution is basic. PH of 0.01% aqueous solution =10.5. The vapor forms an explosive mixture with the air. This product is poisonous, irritates skin and mucous membrane, and causes gangrene. When inhaled, it has an anesthetic effect but does not cause blood poisoning. The rats were LD50710mg/kg orally.
The maximum permissible concentration in the workplace is 10×10-6. Methylcyclohexane was co-heated with hydrogen iodide in a sealed tube at 200℃. Methylcyclohexamine and a small amount of dimethylcyclohexamine were co-heated with dimethyl sulfate in ethyl ether. The hydrochloride reacted with sodium nitrite to obtain cyclohexanol, and reacted with excessive ammonia and zinc chloride to obtain 2-methylpyridine.